RESEARCH PAPER
Laser-modified hydroxyapatite coating on titanium
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1
Katedra i Klinika Protetyki Stomatologicznej i Gerostomatologii, Uniwersytet Medyczny im. K. Marcinkowskiego w Poznaniu
2
Department of Therapeutic Dentistry, Danylo Halytsky Lviv National Medical University, Ukraine
3
Instytut Chemii i Elektrochemii Technicznej, Politechnika Poznańska
4
Wielkopolskie Centrum Zaawansowanych Technologii, Uniwersytet im. Adama Mickiewicza w Poznaniu
5
Zakład Metrologii i Systemów Pomiarowych, Instytut Technologii Mechanicznej, Politechnika Poznańska
Submission date: 2022-11-09
Final revision date: 2022-12-05
Acceptance date: 2022-12-12
Publication date: 2022-12-12
Corresponding author
Magdalena Łukaszewska-Kuska
Katedra i Klinika Protetyki Stomatologicznej i Gerostomatologii, Uniwersytet Medyczny im. K. Marcinkowskiego w Poznaniu
Prosthodontics 2022;72(4):333-340
KEYWORDS
TOPICS
ABSTRACT
Introduction:
Ceramic coatings on titanium
endoosseous implants are known for their
osteoinductive and osteoconductive properties.
Unfortunately, such coating, especially one
obtained during plasma spraying technique, can
detach itself and impair the osseointegration
process of the titanium implant.
Aim of the study:
To assess the influence of
laser modification of electrochemically deposited
hydroxyapatite coating on titanium.
Material and methods:
Hydroxyapatite
coating on titanium was prepared by means of
electrodeposition. The coating was then modified
with a femtosecond laser irradiation in two different regimes (varied power, speed, frequency)
(1-1, 2-2). Two different surface modifications
thus obtained were analysed in terms of
topography, roughness, chemical composition
and hydrophilicity.
Results:
Two different morphologies of
hydroxyapatite coating could be observed on
the SEM micrographs. 2-2 laser modification
did not change the coating morphology while
1-1 processing resulted in creation of laserinduced periodic surface structures (LIPSS)
with characteristic parallel microgroves and
hydroxyapatite crystals sintered into spherical
structures. 1-1 laser processing changed the
concentration of O, Ca and P on the sample
surface. The roughness of both samples was
comparable relative to the Ra parameter. Both
surfaces were hydrophilic with sample modified
with 1-1 processing had contact angle two times
smaller than for 2-2 processing.
Conclusions:
1-1 laser-modified hydroxyapatite
coating presents surface properties potentially
favourable for biological reaction. Further
studies on animal models are necessary to verify
this conclusion in vivo.